Stardock Not Opening in Second User Account

I have Stardock 8 running quite happily on my Win8 desktop computer.

 

I have added a second User Account in Windows for use by my wife. Her account opens into Windows desktop and not the Stardock desktop.

 

What do I need to do so that when she boots the computer and loads her account - Stardock loads the Win7 replica desktop (as it still does when I load my original account).

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